The incident occurred in the catalytic hydrotreatment plant of an oil refinery. The plant, which began operations in September 1997, has a capacity of 1650 tons/day of light fuel oil and 1450 tons/day of heavy fuel oil. The plant was designed to desulfurize the light and heavy fuel oil fractions produced in the refinery by treating them with high-pressure hydrogen over a catalyst to remove sulfur (producing hydrogen sulfide as a byproduct). The plant has two heating/reaction/fractionating sections to treat the two fuel oil fractions, but a single gas purification and compression section for the recycled hydrogen gas.

The heavy fuel oil reactor feedstock from the vacuum distillation plant is sent to the heavy fuel oil treatment section through three pipelines equipped with flow view more

Hydrogen alarms went off in a research laboratory and the fire department was called, but no hydrogen leak was detected. The hydrogen system was leak-checked with helium and found to be leak-free except for a very small leak in the manifold area. The manifold leak was fixed, but because of its small size, it was not thought to be the likely source for the hydrogen alarm trigger. While hydrogen was removed from the system for leak-testing, the hydrogen alarm went off again, and again the fire department responded. There was no hydrogen present in the system to trigger this alarm. Other sources within the building were checked to see what may have set off the alarm, but none were found. One research area uses small amounts of hydrogen, but laboratory logs indicate that none was being view more

During an external review of the facility safety basis document, it was identified that the accident analysis for the pool cell area hydrogen explosion did not account for release of stored hydrogen from the pool cell water as the temperature of the water increases. The analysis only accounted for the hydrogen generated by radiolysis. A loss of pool cell cooling occurring concurrently with a loss of ventilation would result in a higher concentration of hydrogen in the pool cell area than calculated in the safety basis. The safety basis document is being revised to account for the increase in hydrogen concentration.

First responders were dispatched to the waterfront area to investigate a possible explosion on an 85-foot dinner cruise boat that was moored there. Upon arrival, the incident commander noted that nothing out of the ordinary was visible on the exterior of the boat. A crew was sent to the interior of the boat to investigate. The boat was powered by diesel engines and there were no compressed gas cylinders on board.

After further investigation, it became apparent that the explosion had come from the battery compartment in the hull of the boat. The responders concluded that one of the batteries had been giving off hydrogen gas, which gradually built up inside the compartment. Since the compartment was not vented, the gas had nowhere to go. It found an ignition source (possibly a view more

Overview: A hydrogen leak and explosion occurred due to the installation of an incorrectly sized gasket at the suction line of a hydrogen compressor in a refinery hydrodesulfurization plant. The incorrectly sized gasket was mounted during the startup of the plant in 2001 and had never being inspected nor replaced.

Incident synopsis: The operating conditions were stable when the operator received an alarm indicating pressure loss in the circuit. He immediately instructed his field personnel to inspect the area. The hydrogen leak was confined inside the compressor room because the walls and roof were not provided with ventilation devices. An explosion occurred, causing two fatalities and the destruction of the compressor room and some of the surrounding area.

Spent platinum catalyst is recovered from corrugated stainless steel by chemical stripping and recovery. The process is completed by placing the material in lined tanks filled with hydrochloric acid (HCl). Approximately 500 pounds of corrugated stainless steel with platinum coating was inserted into a HCl leaching bath. Prior to starting the process, the supervisor tested the material for reactivity for a period of one hour, and the material showed very little reactivity. Operators began setting up three 500-gallon tanks, each containing the corrugated material. The material was covered with water and 4-5 inches of HCl was then added to the tank. When all three tanks were set up and there was only minimal reactivity observed (occasional bubbles), the operators left the area.

An view more

A fire occurred in a continuous-feed autoclave system (fixed-catalyst-bed tubular reactor) when the rupture disc released, discharging hot oil, oil distillates, and hydrogen gas out a vent pipe into the autoclave cell. The flammable mixture was discharged directly into the cell because there was no system in place to catch or remotely exhaust the autoclave contents. The oil and gas ignited in a fireball that, in turn, ignited nearby combustibles (cardboard and paper), causing a sustained fire. The hydrogen gas and autoclave system were shutoff immediately. However, a lecture bottle containing hydrogen sulfide was heated by the surrounding fire and ultimately ruptured with enough force to cause facility structural damage. (Lecture bottles do not have a pressure-relief device.) The view more

An explosion occurred in a 90-ton-per-day incinerator at a municipal refuse incineration facility. Three workers were seriously burned by high-temperature gas that spouted from the inspection door, and one of them died 10 days later. The accident happened during inspection and repair of the furnace ash chute damper. The workers injected water to remove some blockage, and the water reacted with incinerated aluminum ash to form hydrogen, which caused the explosion.

Workers noticed that the post-combustion zone was full of ash and the ash pusher was not working properly, so they tried to remove the ash from the inspection door with a shovel. They discovered a solid layer of "clinker", which is formed by solidification of molten material such as aluminum. The explosion view more

A hydrogen explosion and fire occurred in the benzene unit of a styrene plant in a large petrochemical complex. The unit was being restarted following a scheduled maintenance shutdown. The explosion followed the release of about 30 kilograms of 700-psig hydrogen gas from a burst flange into a compressor shed. Two men were killed and two others were injured. If it had not been a holiday, the death toll and injuries would probably have been much worse.

The operators were bringing the plant online and increasing the hydrogen circulation pressure. About 10-15 seconds before the explosion, they heard a pop and then a loud hiss of pressure being released within the compressor shed. Witnesses reported seeing a white flash and then a large fireball. The fires burned out in 2-3 minutes, view more

Unit 1 Plant power was stable at 90% following a plant startup. The Auxiliary Operator (AO) performed a pre-job brief with shift management before adding hydrogen to the main generator. While performing the addition, the AO attempted to verify open a half-inch hydrogen addition valve. The AO was unable to move the valve by hand and mistakenly assumed the valve was stuck on its closed seat. The valve is a normally open valve and the procedure step was to verify the valve was, in fact, open. The AO obtained a pipe wrench to assist in freeing the valve off of its "closed" seat. Using the pipe wrench, the valve handwheel was turned in the open direction. The AO attempted to open the valve by hand again. Unable to move the valve by hand, the pipe wrench was used to further open view more