Hydrogen and chlorine concentrations at a certain plant are measured once each shift. On the morning of the explosion, the hydrogen concentration in the chlorine header leaving the cell bank was 0.47 percent. After passing through the chlorine coolers and liquid/gas separators, the hydrogen concentration of the gas streams increased to 2.5-3.2 percent H2, i.e., 63-80 percent of the lower flammability limit.
About 5 hours after the measurements were made, the DC power to the electrolysis cell bank was shut down because of intermittent power supply problems. At that time, a low-order explosion was heard from the chlorine dryer area of the plant. Thirty seconds later, chlorine gas began escaping from the chlorine header pumps, and another explosion occurred in the electrolysis cell view more