A distillate dewaxing unit at an oil refinery was undergoing hot hydrogen regeneration of the catalyst when an explosion occurred. Catalyst regeneration is a periodically performed procedure, in which the normal liquid hydrocarbon feed is stopped and a hydrogen-rich gas mixture is fed through the catalyst bed for which the normal operating temperature is raised from 700F to 800F. During the catalyst regeneration process the reactor pressure is increased from normal operating levels just below 600 psig to about 640 psig. A pipe failure occurred as a sudden and complete rupture of the 10-inch diameter line at the exit of one of the two reactors. Security video revealed that the release rapidly exapnded and the hot gas mixture ignited shortly after rupture. A shock wave from the resulting view more

A chemical plant experienced a valve failure during a planned shutdown for maintenance that caused hydrogen to leak from a valve and catch fire. Four chemical reactor chambers in series were being emptied of liquid using hydrogen gas as part of a maintenance procedure. Two heater valves were opened allowing 3000 psi hydrogen to flow in reverse direction to purge the reactor system for approximately 25 minutes. At completion of the purging process, a "light" thud was heard as the reactor empty-out valves are being closed. Smoky vapor was observed coming out of one of the reactor empty-out valves and the valve closing was stopped by the operator. The operator summoned a second operator for help at which time a second "loud" thud was heard with a much larger light and view more

Operators in a powdered metals production facility heard a hissing noise near one of the plant furnaces and determined that it was a gas leak in the trench below the furnaces. The trench carried hydrogen, nitrogen, and cooling water runoff pipes as well as a vent pipe for the furnaces.

Maintenance personnel presumed that the leak was nonflammable nitrogen because there had recently been a nitrogen piping leak elsewhere in the plant. Using the plant's overhead crane, they removed some of the heavy trench covers. They determined that the leak was in an area that the crane could not reach, so they brought in a forklift with a chain to remove the trench covers in that area.

Eyewitnesses stated that as the first trench cover was wrenched from its position by the forklift view more

In the fall of 2007, the operations team began a procedure (a written procedure was being followed) to sample the liquid hydrogen (LH2) storage vessels ("tanks"), and associated transfer system. This procedure was being performed to determine the conditions within the system, and if necessary, to purge the system of any excess gaseous hydrogen (GH2) in preparation for reactivation of the system. The system had not been used since 2003.

The LH2 storage system contains two (2) spherical pressure vessels of 225,000 gallons in volume, with a maximum working pressure (MAWP) of 50 psig. Eight-inch transfer piping connects them to the usage point. Operations began with activation of the burnstack for the LH2 storage area. Pneumatic gaseous nitrogen (GN2) systems in the view more

A leaking liquid hydrogen cryogenic pump shaft during the process of filling a gaseous tube delivery trailer to 2400 psi at a liquid hydrogen transfilling location caused a series of explosions and a fire. After approximately 30 minutes of filling, the operator heard a single loud explosion and then saw flames and ripples from heat generation near the ground in the hydrogen fill area. The operator quickly actuated the emergency alarm system that shut down the cryogenic pump and closed the air-actuated valves on the cryogenic pump supply line. After this shutdown, three smaller explosions were heard as well as the sound of gas releasing from a safety relief valve. The fire department was called to the scene and participated in the final shutdown of the hydrogen system as the fire was view more

A valve packing started to leak during cold ambient temperatures. A technician was dispatched. He first reduced the pressure to minimize the release and then re-tightened the packing to stop the leak.

The hydrogen sensor at a hydrogen fueling station detected a slight leakage from the ground packing of the flow control valve during refueling. The refueling operation was stopped immediately. The leak was stopped by tightening the ground packing sealing screw, but it started leaking again in about a week.

The flow control valve was disassembled and inspected. Dust was found at the ground seal and the packing was distorted. Leakage was believed to be due to the dust invasion and repeated tightening of the sealing screw. The packing had been used for four years and two months without replacement.

The bulkhead between a liquid hydrogen tank and a liquid oxygen tank failed due to a series of events. Air services to the building were shut down for repairs and the facility had switched to an emergency nitrogen supply. Failure to switch back to service air when it became available, led to the mishap.

The emergency supply became depleted and two valves in the normal nitrogen purge system failed in the open position, releasing the high-pressure nitrogen gas from the manifold into the liquid hydrogen tank. The gas flow raised the liquid hydrogen tank pressure to 4.5 psig. That was sufficient to rupture the bulkhead wall.

A solution of potassium carbonate was being drawn off to an inventory tank for a turnaround/shutdown maintenance activity at a refinery's hydrogen production unit. On the day of the incident, the solution level in the tower wasn't checked as it should have been, which resulted in hydrogen gas flowing back into the tank until the increased pressure caused the tank to explode. The direct cause of the incident was the workers neglecting to check the solution level in the tower. It is not known whether the potential for backflow of hydrogen gas into the inventory tank was understood beforehand or not.

Incident Synopsis
An explosion occurred due to unexpected backflow of hydrogen gas while a solution of potassium carbonate was being drawn off to an view more

A laboratory technician died and three others were injured when hydrogen gas being used in experiments leaked and ignited a flash fire.

The incident occurred in a 5,700-square-foot, single-story building of unprotected non-combustible construction. The building was not equipped with automatic gas detection or fire suppression systems.

Employees in the laboratory were conducting high-pressure, high-temperature experiments with animal and vegetable oils in a catalytic cracker under a gas blanket. They were using a liquefied petroleum gas burner to supply heat in the process.

Investigators believe that a large volume of hydrogen leaked into the room through a pump seal or a pipe union, spread throughout the laboratory, and ignited after coming into contact with the view more