A distillate dewaxing unit at an oil refinery was undergoing hot hydrogen regeneration of the catalyst when an explosion occurred. Catalyst regeneration is a periodically performed procedure, in which the normal liquid hydrocarbon feed is stopped and a hydrogen-rich gas mixture is fed through the catalyst bed for which the normal operating temperature is raised from 700F to 800F. During the catalyst regeneration process the reactor pressure is increased from normal operating levels just below 600 psig to about 640 psig. A pipe failure occurred as a sudden and complete rupture of the 10-inch diameter line at the exit of one of the two reactors. Security video revealed that the release rapidly exapnded and the hot gas mixture ignited shortly after rupture. A shock wave from the resulting view more

An employee at a soap manufacturing plant died in a flash fire outside the facility's hydrogenation building. Responding personnel encountered a fire at the base of the plant's hydrogen storage towers, and they found the victim, who was burned over 90 percent of his body, some 50 feet away.

Officials determined that a pipe connection failed and that hydrogen, pressurized at 1,800 psi, ignited when it was released into the atmosphere, killing the plant operator.

According to reports, the pipe connection failure stemmed from pressures higher than design tolerance, which in turn were the result of over tightening that occurred during routine maintenance replacement. The new bolts were stronger than those they replaced, and the threads of the nuts had been partially view more

A hydrogen explosion occurred at a plant, damaging a wall adjacent to the hydrogen storage assembly. The investigation revealed that the explosion was the consequence of deficiencies in components integral to the hydrogen storage assembly, and that this assembly belonged to a supplier contracted to provide hydrogen to the plant. The analysis revealed that had the supplier properly installed and maintained this equipment, this incident would have been prevented. By receiving assurance, on an ongoing basis, that the supplier was properly maintaining this equipment, the company could have also reduced the chance of occurrence of this incident.

A hydrogen supplier was awarded a contract in 1990 to supply the plant with hydrogen as well as to provide view more

During operation of a succinic acid plant, hydrogen leaked from a mounting joint on a safety valve at the upper part of a reactor, which generated a hydrogen flame. Prior to the incident, the safety valve was removed and reattached during an inspection at a turnaround shutdown. An incorrectly sized, smaller gasket was installed on the joint, and the tightening force on the bolts was inadequate. Therefore, a gap was generated as time went by and un-reacted hydrogen leaked.

In the case of many leak tests after construction, a leak is checked by a soap test after pressurizing piping and facilities for the test. (A soap test is conducted by pouring soap suds at the place to be checked (mainly a joint part) after pressurizing. If bubbles are found, view more

A hydrogen leak and fire occurred due to the installation of an incorrectly sized gasket at a solvent manufacturing plant. A worn gasket was accidentally replaced with a new gasket that was smaller than the standard one, and the system could not withstand the operational pressure of the hydrogen, causing the hydrogen to leak and ignite a small fire. Furthermore, a nearby gasket was damaged by the fire, causing a larger quantity of hydrogen to leak, and the fire spread. As nitrogen was substituted for the combustible hydrogen gas in the piping at an early stage of the fire, damage was limited to the immediate area. If the hydrogen had not been quickly purged from the system, the fire damage would have been greater. It is assumed that gasket management at a turnaround view more